Question: How does baking powder differ from baking soda?
Answer:
Baking soda is a single compound which has sodium
hydrogen carbonate which is alkaline
(basic) in nature
Baking
powder is a mixture of sodium
hydrogencarbonate and a mild edible(eatable) acid such as tartaric acid. When
baking powder mixes with water, then the sodium hydrogencarbonate reacts with
tartaric acid to evolve carbon dioxide gas which gets trapped in the wet dough
and bubbles out slowly making the cake to rise and hence 'soft and spongy'.The
equation which takes place can be shown as:
NaHCO3 +
H+ ----> Na+ + CO2 + H2O
Question: What will happen if heating is not controlled while preparing
Plaster of Paris from gypsum?
Answer:
It may be noted that the temperature should be controlled
carefully. It should not be allowed to rise above 152°C (425K) because, if
whole of the water is lost then anhydrous calcium sulphate is produced, which
is called dead burnt plaster and it does not have the properties of Plaster of
Paris.
Question: Explain how pH change in the
river water can endanger the lives of aquatic animals.
Answer:
Living organisms can survive only in a narrow range of pH
change. When pH of rain water is less than 5.6, it is called acid rain. When
acid rain flows into the rivers, it lowers the pH of the river water. The
survival of aquatic life in such rivers becomes difficult.
Question: What are the two main ways in which common salt (sodium chloride)
occurs in nature? How is common salt obtained from sea water? Explain
Answer:
Salt exists in two forms in nature i.e. in sea water and
in the form of Halite a mineral rock of common salt. Common salt can be
prepared by evaporation of sea water. Sea water is collected in division of
land and it is allowed to evaporate under sunlight. Water is evaporated leaving
behind mixtures of salt, form which common salt is separated by dissolving it
in suitable reagent and then, recrystallizing salt from the solution.
Question: Why aqueous solution of sodium carbonate is basic in
nature?
Answer: Sodium bicarbonate is an amphoteric compound. Aqueous solutions are mildly alkaline due to the formation of carbonic acid and hydroxide ion:
NaHCO− 3 + H2O → H2CO3 + OH−
Question: Why is an aqueous solution of ammonium chloride acidic in
nature?
Answer:
A basic component is the one that produces hydroxide (OH-) ions when
dissolved in water. In aqueous solution of ammonium chloride,
ammonium ions (NH4+) first associate with H2O and form
ammonia and hydroxide ions.
NH4Cl
+ H2O = NH4+ + HCl ( equation 1)
NH4+ +
H2O = NH3 + OH- (equation 3)
Since
ammonium ions produce hydroxide ions, NH4+ are considered to be
the basic components.
Question: Dry ammonia has no action on litmus paper
but a solution of ammonia in water turns red litmus paper blue. Why is it so?
Answer: In dry state Ammonia contains no hydroxyl ions. On dissolving in
water, it forms NH4OH which dissociates to give NH4 + and OH-ions.
Thus solution becomes basic and turns red litmus paper blue.
NH3 (g) + H2O (l) ---------------> NH4OH (aq)
NH4OH (aq) --------------> NH4+ (aq) + OH- (aq)
Question: What happens when (a)
Solid sodium hydrogen carbonate is heated, (b) Chlorine gas is passed through
dry slaked lime, (c) Gypsum is heated to a temperature of 373 K?
Answer:
(a) When Solid sodium hydrogen carbonate is heated from sodium chloride Na2CO3.10H2O
(washing soda).
2NaHCO3
--------Heat----------> Na2CO3
+H2O+CO2
(b)
when Chlorine gas is passed through dry slaked lime, Bleaching powder is
produced. Bleaching powderis represented as CaOCl2, though the actual
composition is quite complex.
Ca(OH)2
+ Cl2 → CaOCl2 + H2O
(c)
if Gypsum is heated to a temperature of 373 K it forms plaster of Paris, CaSO4
½ H2O
CaSO4
2H2O --- -373 K ------> CaSO4 ½
H2O + 3/2 H2O
Question: Give the Names of Raw Materials
that are required for the manufacture of
washing soda by solvay process. Write the reactions involved in the process.
Answer: Common salt :
NaCl.Sodium chloride. Ammonia : NH3
.Ammonia
Lime Stone :
CaCO3.Lime stone (Calcium carbonate)
H2O + NH3 + NaCl + CO2 -----------> NaHCO3 + NH4Cl
2NaHCO3 ----------
Heat------> Na2CO3+ CO2+H2O
CaCO3 -----------
Heat > CO2+CaO
CaO + H2O ---------> Ca (OH)2
Ca(OH)2+ 2NH4Cl
------------> CaCl2 +2NH3+2H2O
Question: What is efflorescence? Name one compound which
shows efflorescence? support your answer with reaction?
Answer: The processes of
loosing water of crystallization, when the substance is exposed to air for long
time to form anhydrous or monohydric
substance is called as efflorescence.
Na2CO3 10 H2O, Sodium
carbonate deca hydrate is one example.
Na2CO3 , 10 H2O -------------->Na2CO3 H2O +
9H2O
Question: why is calcium sulphate hemihydrate called
‘Plaster of Paris’ ?
Answer:
Plaster of Paris gets its name from large gypsum deposits
in Montmartre in Paris. We know that plaster of Paris, which is chemically
calcium sulphate hemihydrate is obtained by heating gypsum. So the origin of
the name 'Plaster of Paris' is the fact that the source material gypsum is
found in large deposits at Montmartre in Paris
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